A Promising New Schiff Base-like Ligand for the Synthesis of Octahedral Iron(II) Spin Crossover Complexes
نویسندگان
چکیده
A new tetradentate Schiff base-like ligand H2L (1) ((E,E)-dimethyl-2,2′-[1,2-phenylenebis(aminomethylidyne)]bis[3-oxobutanoate]) was synthesised and structurally characterised. Its reaction with iron(II) acetate leads to the formation of the octahedral N2O4-coordinated complex [FeL(MeOH)2] (2). The complex is a pure high-spin (HS) compound as is evident from magnetic measurements and X-ray crystallography.
منابع مشابه
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